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Updated 26/02/2015 at 20:42 GMT
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Besiktas it is, then, that book their place in the last 16 of the Europa League... Heartbreak for Liverpool, but you have to say the home side probably deserved it as they have been on top in this game since the beginning of the second half.
Lovren steps up for Liverpool but he blazes his strike well over the bar, meaning Besiktas have won the shoot-out 5-4!
Arslan, who scored earlier, finds the back of the net to make it 5-4 to Besiktas. Liverpool under real pressure to score now...
Allen makes it 4-4 with a good finish. It's effectively sudden death now...
Another great penalty as Hutchinson finds the top corner... There have been some great efforts in this shoot-out.
Can picks out the bottom corner with a great penalty for Liverpool. Who is going to crack first?
The goals keep on coming, with Kavlak the next to find a way past Mignolet. 3-2 to the Turkish side.
It's 2-2 as Lallana finds the back of the net for Liverpool. It's getting rather tight...
2-1 to Besiktas as Tore sends the ball past Mignolet, who did guess the right way. Pressure on Liverpool now...
Lambert is first for Liverpool and the substitute also converts, blasting his penalty into the top corner. Great penalty.
So here come the penalites... Ba steps up first for Besiktas and sends Mignolet the wrong way to edge Besiktas ahead.
120'
And there sounds the whistle for full-time of extra-time... Penalties it is. Will Liverpool be victorious in a shoot-out in Istanbul once again?
119'
Penalties fast approaching...
118'
Liverpool win a free-kick in a dangerous position once more, but they waste it again. The Reds really don't look like scoring...
117'
Ba has missed a few chances today but he has led the line very well for Besiktas and given the Reds defence something to think about.
115'
Ba with a chance again as Besiktas burst forward through the middle, but his strike is sent over the bar.
114'
Saying that, it is Besiktas who do look like they could find a breakthrough once more... Tore continues to be a threat down the left, with his balls into the box causing Liverpool some problems.
113'
Less than eight minutes remaining and both teams would probably settle for penalites at this stage as neither are prepared to make any late gambles.